Projects



Glass Transition


The transition from a liquid to a glass is characterized by a drastic slow-down of structural relaxation and transport, while the structure remains amorphous and seemingly unchanged. In this project we investigate connections between structural properties of supercooled liquids and their emerging dynamics using computer simulations, machine learning and mode-coupling theory.

Specific topics and collaborators


Dynamic Coarse-Graining and Non-Markovian Dynamics


Coarse-graining describes the process in which a high-dimensional microscopic system is reduced to a model with much fewer degrees of freedom. One important property of the equations of motion of this coarse-grained model is their non-Markovianity: The missing knowledge on the motion of the neglected degrees leads to the emergence of memory in the dynamics of the coarse-grained variables. We study how these memory effects can be quantified in both equilibrium and non-equilibrium systems. Furthermore we develop tools to simulate particles with non-Markovian dynamics. (See Introducing memory in coarse-grained molecular simulations for a recent review.)

Specific topics and collaborators


Confinement


Liquids in confinement behave very different from their bulk counterparts. A well known phenomenon is for example the wetting at the boundaries, which leads to non-homogeneous densities and layering, but also dynamical properties are strongly affected by confinement. We study structural properties of liquids in extreme confinement by fundamental-measure theory and simulations. We also investigate confined glasses and confinement-induced crystallization by theory, simulations and experiments.

Specific topics and collaborators


Non-Equilibrium Dynamics


Non-equilibrium systems, such as active suspensions or externally-driven particles, show phenomenology which goes far beyond equilibrium physic. Importantly, dynamical properties such as friction and memory do not only affect liquid transport in non-equilibrium systems but can also influence the emerging structural properties of liquids. We are interested, in how complex dynamical properties, such as viscoelasticity, affects collective motion of active particles, but also more abstract concepts known from equilibrium physics, including fluctuation-dissipation theorems.

Specific topics and collaborators